She said: 'This programme started when I was born.'
Jessie added that she wanted to: 'Shock people. I wanted to do something that wasn't going to last five minutes and it's fun.
After appearing on the show Jessie didn't waste time thanking fans and tweeted: 'I am soooo thankful to everyone who has donated @rednoseday and supported me tonight! My heart is filled with happiness! Lets make a change! X'
During the programme a segment aired showing Jessie visiting some of the charities that Comic Relief helps.